Make sure that you are viewing the image at 100%, or, if it is a larger sized print, 50%. To complete the first, large detail sharpening pass go to Filter>Sharpen>Unsharp Mask. Select a Threshold of 1, a radius of .7 to 1.0 for web images and 1.5 to 2.5 for prints, and an amount in the 50 to 75 % range. I find it helpful to check and uncheck the preview box to dial in the right amount of sharpening. Select OK when you are finished. Now to sharpen the fine edges and details, go to Filter>Sharpen>Smart Sharpen (or Unsharp Mask again if your version of PS is pre CS2). Set the Remove box to Lens Blur, the radius to 0.1 for screen and web size images or .2 to .4 for prints, depending on how large the print will be, and finally, adjust the amount to 100 to 140% or until the desired sharpness is achieved.
I find that this two-pass sharpening technique does a great job of targeting sharpening to both the larger and finer details separately, especially for images that will be displayed on a screen. As with any sharpening technique, knowing how far to go without going too far is the key and some experimentation is needed to determine the best combination of adjustments for each individual image. Below are samples of a screen sized image. The first is not sharpened, the second is sharpened appropriately using this technique and the final image is over sharpened in my opinion.

